A new approach to fabricate the Mn(ii)-based magnetic refrigerant through incorporation of a diamagnetic LiO<sub>4</sub> spacer.
| Author | |
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| Abstract | :
A new 3D MOF [MnLi2(ip)2(H2O)2] (1) with a 1D heterometallic inorganic Mn(ii)-Li(i) chain is reported. With the assistance of diamagnetic {LiO4} connectors, which separate the paramagnetic Mn(ii) ions and act as magnetic spacers, very weak magnetic interactions were obtained. Remarkably, 1 showed a significant magnetocaloric effect (MCE) with a large entropy change value of 30.4 J kg-1 K-1 for ΔH = 8 T at 2 K. |
| Year of Publication | :
2018
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| Journal | :
Dalton transactions (Cambridge, England : 2003)
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| Date Published | :
2018
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| ISSN Number | :
1477-9226
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| DOI | :
10.1039/c7dt04820c
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| Short Title | :
Dalton Trans
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